Hydrogen Atom Energy Levels Calculator

Explore Bohr levels with flexible hydrogenic options today. Compute photons, wavelengths, and series names easily. Validate labs, homework, and spectroscopy designs in minutes anywhere.

Calculator Inputs

Choose a single bound-state level or a photon transition.
Use Z=1 for hydrogen; higher values for hydrogen-like ions.
Typical spectroscopy uses n up to about 20.
For emission, nᵢ is usually greater than nᶠ.
The lower level sets the spectral series name.
Results appear above this form after submission.

Example Data Table

Scenario Inputs Key output
Ground state energy Z=1, n=1 E₁ ≈ −13.606 eV
First excited level Z=1, n=2 E₂ ≈ −3.401 eV
Balmer-α transition Z=1, nᵢ=3 → nᶠ=2 λ ≈ 656 nm (visible red)
Lyman-α transition Z=1, nᵢ=2 → nᶠ=1 λ ≈ 122 nm (ultraviolet)
Values are approximate and depend on constants and rounding.

Formula Used

In the Bohr model for a hydrogen-like ion, the bound-state energy for level n is:

En = −ER · Z² / n²

For a transition between levels nᵢ and nᶠ, the photon energy is:

ΔE = Ef − Ei, and |ΔE| = h·f = h·c/λ

A common line estimate uses the Rydberg relation: 1/λ = R · Z² · (1/nlow² − 1/nhigh²).

How to Use This Calculator

  1. Select Single level energy to compute En for a chosen n.
  2. Select Transition photon to compute ΔE, frequency, and wavelength.
  3. Enter Z. Keep Z=1 for hydrogen; adjust for ions.
  4. Provide the requested quantum numbers. Use integers for n, nᵢ, and nᶠ.
  5. Press Calculate. The result appears above the form.
  6. Use Download CSV or Download PDF to save outputs.

Notes and Practical Tips

Hydrogen Energy Levels and Spectral Transitions

1) Bohr model overview

Hydrogen’s simplest bound-state picture comes from the Bohr model, where the electron occupies discrete orbits labeled by the principal quantum number n. Each n corresponds to a fixed energy En, so the atom can only absorb or emit photons whose energies match differences between two levels.

2) Energy level scaling with n

In a hydrogen-like system, energies scale as −Z²/n². Doubling n makes the magnitude of En four times smaller, so higher levels cluster close to zero. This spacing trend explains why high-n states are easier to ionize and why spectral lines compress toward series limits.

3) Ionization energy and the continuum limit

The ionization threshold is defined at E = 0, where the electron is no longer bound. For hydrogen, the ground-state binding energy is about 13.6 eV, which is the energy needed to remove the electron completely. As n increases, En approaches zero, representing states near the continuum.

4) Transition energy and photon properties

A transition from ni to nf produces a photon with |ΔE| = h·f = h·c/λ. Emission typically occurs when ni > nf, releasing energy as light. Absorption occurs when the atom gains energy and moves upward.

5) Spectral series and wavelength regions

The lower level sets the spectral series: Lyman (n=1) lies in ultraviolet, Balmer (n=2) appears in visible and near‑UV, and Paschen (n=3) is infrared. This calculator labels the series and reports wavelength in nanometers for quick region identification.

6) Constants and numerical accuracy

Results depend on the constants used, especially the Rydberg value and the energy conversion between eV and joules. Small differences can appear between a wavelength computed from |ΔE| and one computed from the Rydberg relation. Both are useful cross-checks for coursework and lab reports.

7) Typical laboratory applications

In spectroscopy experiments, measured wavelengths can be mapped to n transitions by scanning plausible (ni, nf) pairs and matching λ. For plasma and discharge tubes, the same approach helps identify hydrogenic ions where Z > 1, shifting lines by Z².

8) Data snapshot for common lines

A classic reference is Balmer‑α: ni=3 → nf=2 yields λ near 656 nm. Lyman‑α: 2 → 1 is near 121.6 nm. These values are widely used for calibration checks and for validating the expected spectral series limits.

FAQs

1) Why are hydrogen energy levels negative?

The zero reference is the free electron at infinity. Bound states have lower energy, so En is negative. The magnitude indicates how much energy is required to ionize that level.

2) What does the effective charge Z represent?

Z is the nuclear charge seen by the electron. Hydrogen uses Z=1. Hydrogen‑like ions, such as He⁺, use Z=2, which increases binding energies and shifts wavelengths by a factor of Z².

3) Why does the calculator show two wavelengths?

One wavelength comes from |ΔE| and fundamental constants. The other uses the Rydberg line formula. Slight differences can occur due to constant selection, reduced‑mass effects, and rounding.

4) What n values are reasonable to use?

Most introductory problems use n up to 20. Larger n values are allowed for completeness, but level spacing becomes tiny and results become sensitive to rounding and to physical effects not included here.

5) How do I interpret emission versus absorption?

If ΔE = Ef − Ei is negative, the atom emits a photon. If ΔE is positive, the atom must absorb a photon to make the transition upward.

6) Does this include fine structure or Lamb shift?

No. It uses the basic hydrogenic energy scaling. Fine structure, Lamb shift, hyperfine splitting, and external field effects require more advanced quantum models and additional inputs.

7) How can I match an observed wavelength to levels?

Choose a likely series by region (UV, visible, IR), then test ni and nf combinations until the calculated wavelength matches your measurement within uncertainty.

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